7137-77-1Relevant articles and documents
Direct benzylation of amines with benzylic alcohols catalyzed by palladium/phosphine-borane catalyst system
Onodera, Gen,Kumagae, Hidenobu,Nakamura, Daiki,Hayasaki, Takuto,Fukuda, Tsutomu,Kimura, Masanari
supporting information, (2020/11/04)
Direct catalytic benzylation of amines with benzylic alcohols to give benzylamines has been newly developed by using palladium/phosphine-borane catalyst system. In this catalytic reaction, the linking between both phosphine and borane moieties in the ligand is very important. Hydroxy group of benzylic alcohols is activated by Lewis acidic borane to form a benzylpalladium intermediate which is attacked by amines to give benzylamine products.
Application of lanthanoid catalysts for the synthesis of Michler's hydride
Andrews, Philip C.,Junk, Peter C.,Kemppinen, K. Peter,Konstas, Kristina,Tuck, Kellie L.
scheme or table, p. 229 - 233 (2010/04/23)
A series of lanthanoid (Ln3+) based Lewis acid catalysts were investigated as alternatives to other metal based catalysts for the formation of Michler's hydride, 4, 4′-methylenebis(N, N-dimethylaniline) (1). The lanthanoid based Lewis acid cata
Iron-catalysed Oxidation of N,N-Dimethylaniline with Molecular Oxygen
Murata, Satoru,Miura, Masahiro,Nomura, Masakatsu
, p. 116 - 118 (2007/10/02)
N,N-Dimethylaniline is oxidised by molecular oxygen in the presence of a number of iron complexes or salts in acetonitrile to give a mixture of N-methylformanilide and 4,4'-methylenebis(N,N'-dimethylaniline) together with N-methylaniline, the product composition being a marked function of the identity of the iron species employed.