389607-98-1

Basic information

• Product Name: 5-(1-cyclohexenyl)-pentanophenone N,N-dimethylhydrazone
• Synonyms: 5-(1-cyclohexenyl)-pentanophenone N,N-dimethylhydrazone
• CAS NO: 389607-98-1
• Molecular Weight: 284.445
• Mol File: 389607-98-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(1-cyclohexenyl)-pentanophenone N,N-dimethylhydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(1-cyclohexenyl)-pentanophenone N,N-dimethylhydrazone(389607-98-1)
• EPA Substance Registry System: 5-(1-cyclohexenyl)-pentanophenone N,N-dimethylhydrazone(389607-98-1)

Safety Data

• Hazardous Substances Data: 389607-98-1(Hazardous Substances Data)

Upstream product

• 13466-32-5 acetophenone dimethylhydrazone 
• 348135-81-9 1-(3-iodopropyl)cyclohex-1-ene 
• 136425-21-3 2-(1-cyclohexenyl)ethyl methanesulfonate 
• 82201-80-7 1-iodo-2-(1-cyclohexenyl)ethane 
• 13992-92-2 3-(cyclohex-1-en-1-yl)propanenitrile 
• 27338-44-9 3-(cyclohex-1-en-1-yl)propionic acid 
• 63715-12-8 1-(3-mesyloxypropyl)-1-cyclohexene 
• 6975-71-9 1-cyclohexenylacetonitrile 
• 22516-18-3 3-(cyclohex-1-en-1-yl)propan-1-ol 
• 60-12-8 2-phenylethanol 
• 53723-52-7 methyl 1-cyclohexene-1-acetate 
• 3197-68-0 2-(1-Cyclohexenyl)ethanol 

Downstream Products

• 389607-99-2 5-(1-cyclohexenyl)-pentanophenone 

Relevant articles and documents

Stereo- and regioselectivity of cyclization reactions in conformationally restricted epoxy ketones: Evaluation of C- versus O-alkylation process

The intramolecular addition reaction of metal enolates of ketones to oxiranes has been applied to a series of epoxy ketones derived from cyclohexene oxide. γ-Hydroxy ketones (γ-HKs, C-alkylation products) or hydroxy enol ethers (HEEs, O-alkylation products) are obtained, depending on the nature of the cyclic transition state in each case involved and the application of the Fu?rst-Plattner rule. The formation of HEEs by reaction of the same epoxy ketones under acid conditions is also described. In some cases, regioconvergent or chemoselective processes are conveniently obtained.