55520-53-1

Basic information

• Product Name: (3R,4S)-2,3,4,5-Tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole
• CAS NO: 55520-53-1
• Molecular Weight: 392.44
• Mol File: 55520-53-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3R,4S)-2,3,4,5-Tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole(CAS DataBase Reference)
• NIST Chemistry Reference: (3R,4S)-2,3,4,5-Tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole(55520-53-1)
• EPA Substance Registry System: (3R,4S)-2,3,4,5-Tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole(55520-53-1)

Safety Data

• Hazardous Substances Data: 55520-53-1(Hazardous Substances Data)

Upstream product

• 74-96-4 ethyl bromide 
• 55520-53-1 (3R,4S)-2,3,4,5-Tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole 

Downstream Products

• 3469-20-3 2,3-diphenyl-1H-indole 
• 55520-53-1 (3R,4R)-2,3,4,5-Tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole 
• 86211-12-3 N-[(R)-2-((R)-Ethyl-phenyl-phosphinoyl)-1,2-diphenyl-eth-(Z)-ylidene]-N'-phenyl-hydrazine 
• 86211-12-3 N-[(R)-2-((S)-Ethyl-phenyl-phosphinoyl)-1,2-diphenyl-eth-(Z)-ylidene]-N'-phenyl-hydrazine 
• 106-47-8 4-chloro-aniline 
• 51849-78-6 2,3,4r,5-tetraphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole 3c-oxide 
• 86211-10-1 N-[(R)-2-((S)-Methyl-phenyl-phosphinoyl)-1,2-diphenyl-eth-(Z)-ylidene]-N'-phenyl-hydrazine 
• 86211-10-1 N-[(R)-2-((R)-Methyl-phenyl-phosphinoyl)-1,2-diphenyl-eth-(Z)-ylidene]-N'-phenyl-hydrazine 
• 62-53-3 aniline 
• 55520-55-3 (3R,4R)-5-Benzyl-2,3,4-triphenyl-3,4-dihydro-2H-[1,2,3]diazaphosphole 
• 88-74-4 2-nitro-aniline 

Relevant articles and documents

Reactivity of 2H-1,2,3-Diazaphosphole Derivatives: Unexpected Formation of Indoles and New Indolization Reaction

2H-1,2,3-Diazaphosphole derivatives (1) react with alkyl halides to give the corresponding 2,3-disubstituted indoles (3) as the major products (30-40percent yields).Small amounts (15-20percent) of the ring-opened compounds (4) in the two diastereoisomeric Z-configuration are also obtained.During this reaction a cis-(1) trans-(1) isomerization is also observed.Mechanistic explanations of these results have been described and a new general method has been developed for the synthesis of 2,3-disubstituted indoles from ketone arylhydrazones and PCl3.