71193-47-0

Basic information

• Product Name: Benzenamine, 4-methoxy-N-propyl-
• CAS NO: 71193-47-0
• Molecular Formula: C10H15NO
• Molecular Weight: 165.235
• Mol File: 71193-47-0.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-methoxy-N-propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-methoxy-N-propyl-(71193-47-0)
• EPA Substance Registry System: Benzenamine, 4-methoxy-N-propyl-(71193-47-0)

Safety Data

• Hazardous Substances Data: 71193-47-0(Hazardous Substances Data)

Upstream product

• 51-66-1 4-methoxyacetanilide 
• 106-94-5 propyl bromide 
• 369363-23-5 diethyl 2-[(p-methoxyphenyl)(propyl)amino]malonate 
• 107-10-8 propylamine 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 783-08-4 [4-(benzylideneamino)phenyl]methanol 
• 96-96-8 4-methoxy-2-nitroaniline 
• 100-17-4 para-methoxynitrobenzene 
• 123-38-6 propionaldehyde 
• 102-69-2 tri-n-propylamine 
• 104-94-9 4-methoxy-aniline 
• 142-84-7 di-n-propylamine 
• 71-23-8 propan-1-ol 
• 74-85-1 ethene 

Downstream Products

• 55245-23-3 C₁₁H₁₄ClNO₂ 
• 1304501-75-4 4-methoxy-N₂-(4-methoxyphenyl)-N₁,N₂-dipropylbenzene-1,2-diamine 

Relevant articles and documents

Titanium-Catalyzed Hydroaminoalkylation of Ethylene

The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti?C bond of a titanaaziridine is reported.

Direct Aryl C?H Amination with Primary Amines Using Organic Photoredox Catalysis

The direct catalytic C?H amination of arenes is a powerful synthetic strategy with useful applications in pharmaceuticals, agrochemicals, and materials chemistry. Despite the advances in catalytic C?H functionalization, the use of aliphatic amine coupling partners is limited. Described herein is the construction of C?N bonds, using primary amines, by direct C?H functionalization with an acridinium photoredox catalyst under an aerobic atmosphere. A wide variety of primary amines, including amino acids and more complex amines are competent coupling partners. Various electron-rich aromatics and heteroaromatics are useful scaffolds in this reaction, as are complex, biologically active arenes. We also describe the ability to functionalize arenes that are not oxidized by an acridinium catalyst, such as benzene and toluene, thus supporting a reactive amine cation radical intermediate.

A sound shielding through the level three-stage amine instead new method should be secondary amine

The invention discloses a novel method for preparing secondary amine by a reaction of primary amine and tertiary amine. The method comprises the following steps of 1, adding primary amine and tertiary amine into a reaction container according to a mole ratio of primary amine to tertiary amine of 1: 3, adding [(Bt)2*Ir*P(nBu)3]OTf as a catalyst (wherein Bt represents phenylbenzothiazole) into the reaction container, adding an organic solvent into the reaction container, and carrying out a reaction process at a temperature of 120-160 DEG C for 6-12h, wherein a mole ratio of primary amine, tertiary amine to catalyst is 1: 3: 0.01, and 2, carrying out purification by a silica gel column of 200-300 meshes, pre-leaching the silica gel column by 20-50mL of petroleum ether, carrying out elution on the leacheate at a leacheate flowing rate of 1-2mL/min for 3-6h so that the solvent is removed and the corresponding secondary amine product is obtained. A research result shows that the novel method for producing secondary amine by a reaction of primary amine and tertiary amine has the characteristics of mild conditions, high conversion rate and no pollutant. The method solves the problems of the existing secondary amine synthesis method and improves secondary amine synthesis.