7397-46-8 Usage
Description
Methoxydiethylborane is a transparent to light yellow liquid that is utilized in various chemical reactions and analytical studies due to its unique properties.
Uses
1. Analytical Studies:
Methoxydiethylborane is used as a reagent for identifying functional groups in protonated oxygen-containing monofunctional compounds through mass spectrometry. This application is valuable in the field of analytical chemistry for understanding the structure and properties of various compounds.
2. Catalyst in Ring-Opening Metathesis Polymerization / Vinyl Insertion Polymerization:
In the chemical industry, Methoxydiethylborane serves as a reactant involved in studying a catalyst for ring-opening metathesis polymerization and vinyl insertion polymerization. These processes are essential for the synthesis of complex polymers with specific properties.
3. Reformatsky / Quaternary Claisen Condensations:
Methoxydiethylborane is used as a reactant in Reformatsky reactions and quaternary Claisen condensations, which are important for the formation of new carbon-carbon bonds and the synthesis of various organic compounds.
4. Enantioselective Synthesis of Carba-furanose Sugars:
In the field of organic chemistry, Methoxydiethylborane is employed in the enantioselective synthesis of carba-furanose sugars. This application is crucial for the development of chiral molecules with potential pharmaceutical applications.
5. Borane-Mediated Control Radical Polymerization for Synthesis of Fluoropolymers:
Methoxydiethylborane is used as a reactant in borane-mediated control radical polymerization, which is a technique for synthesizing fluoropolymers with controlled molecular weight and architecture.
6. Homologation Reactions with Sulfonium Ylides:
In organic synthesis, Methoxydiethylborane is utilized in homologation reactions with sulfonium ylides, allowing for the formation of new carbon-carbon bonds and the synthesis of various organic compounds.
7. Trialkylborane Promoted Adhesion to Low Surface Energy Plastics:
Methoxydiethylborane is used as a reactant in promoting adhesion to low surface energy plastics, which is an essential application in the plastics and coatings industry for improving the durability and performance of plastic materials.
Check Digit Verification of cas no
The CAS Registry Mumber 7397-46-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,9 and 7 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 7397-46:
(6*7)+(5*3)+(4*9)+(3*7)+(2*4)+(1*6)=128
128 % 10 = 8
So 7397-46-8 is a valid CAS Registry Number.
InChI:InChI=1/C5H13BO/c1-4-6(5-2)7-3/h4-5H2,1-3H3
7397-46-8Relevant articles and documents
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Mikhailov,B.M. et al.
, (1975)
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Noeth,H.,Vahrenkamp,H.
, p. 23 - 36 (1968)
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Syntheses, structures, and coordination of diborylbipyridines and bipyridinediborates
Weis, Norbert,Pritzkow, Hans,Siebert, Walter
, p. 393 - 398 (2007/10/03)
6,6'-Bis(diethylboryl)-2,2'-bipyridine (1a) was obtained in low yield by in situ deprotonation of 2,2'-bipyridine in the presence of diethyl(methoxy)borane. 6,6'-Dilithio-2,2'-bipyridine reacts with various alkoxyboranes leading to bipyridinediborates 2 in good yields. The derivatives 2b and 2c allow the formation of the free diborylbipyridines 1b and 1c. The coordination properties of the diboryl-bipyridines as tetra- functional donor-acceptor compounds have been used for the formation of the copper complex 4 and of the adduct 5 which is built from diborylbipyridine and a dihydroxydiboroxan derivative. The composition of the products follows from spectroscopic data and from X-ray structure analyses for 2f, 4, and 5.
A Novel Method for the In Situ Generation of Alkoxydialkylboranes and Their Use in the Selective Preparation of 1,3-Syn Diols
Chen, Kau-Ming,Gunderson, Karl G.,Hardtmann, Goetz E.,Prasad, Kapa,Repic, Oljan,Shapiro, Michael J.
, p. 1923 - 1926 (2007/10/02)
An in situ method for generating Et2BOCH3 from triethylborane and methanol without using any other catalysts is described.Using the Et2BOCH3 thus generated as a chelating agent, syn 1,3-diols are prepared in > 98 percent stereochemical purity by reducing β-hydroxy-ketones with sodium borohydride