76711-42-7

Basic information

• Product Name: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene
• Synonyms: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene
• CAS NO: 76711-42-7
• Molecular Weight: 206.36
• Mol File: 76711-42-7.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene(76711-42-7)
• EPA Substance Registry System: (E)-2-(4-methoxyphenyl)-1-trimethylsilylethene(76711-42-7)

Safety Data

• Hazardous Substances Data: 76711-42-7(Hazardous Substances Data)

Upstream product

• 938-81-8 N-nitrosoacetanilide 
• 14839-81-7 4-methoxy-N-nitrosoacetanilide 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 6712-20-5 2-(4-methoxyphenyl)-[1,3]dithiolane 
• 41309-43-7 (2-bromovinyl)trimethylsilane 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 100-17-4 para-methoxynitrobenzene 
• 754-05-2 ethenyltrimethylsilane 
• 637-69-4 4-Methoxystyrene 
• 336193-48-7 2-chloro-1-(4-methoxy-phenyl)-2-trimethylsilanyl-ethanol 
• 123-11-5 4-methoxy-benzaldehyde 
• 696-62-8 para-iodoanisole 
• 65343-66-0 Tris(trimethylsilyl)aluminium 
• 768-60-5 4-methoxyphenylacetylen 

Downstream Products

• 22145-09-1 (1E,3E)-1,4-bis(4-methoxyphenyl)buta-1,3-diene 
• 89510-55-4 1-p-nitrophenyl-4-p-nitrophenylbuta-1E,3E-diene 
• 136795-71-6 (1E,3E)-1-(4-methoxyphenyl)-4-(4'-nitrophenyl)-1,3-butadiene 
• 4842-77-7 (2E,4E)-5-(4-methoxyphenyl)-1-phenylpenta-2,4-dien-1-one 
• 65682-02-2 (2E,4E)-1,6-diphenyl-2,4-hexadiene-1,6-dione 
• 1428963-19-2 (1E,3E)-1-(4-methoxyphenyl)-4-(3,5-difluorophenyl)-1,3-butadiene 
• 1104997-33-2 (E)-1-(4-methoxyphenyl)-3,3-diphenyl-1-propene 
• 501-36-0 (E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol 
• 22255-22-7 3,5,4'-trimethoxy-trans-stilbene 
• 5043-91-4 (E)-4-chloro-4'-methoxystilbene 
• 136618-41-2 E-2'-p-methoxystyryl iodide 

Relevant articles and documents

Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex

A palladium complex coordinated with a chiral SIPHOS ligand was evaluated as an efficient catalyst for asymmetric hydrosilylation of β-silyl styrenes with trichlorosilane and 23 1,2-bis(silyl) chiral compounds were produced. Good to excellent enantioselec

Iron-Catalyzed Cross-Coupling of Bis-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and mechanistic investigations

Various substituted bis-(aryl)manganese species were prepared from aryl bromides by one-pot insertion of magnesium turnings in the presence of LiCl and in situ trans-metalation with MnCl2 in THF at ?5 ?C within 2 h. These bis-(aryl)manganese reagents undergo smooth iron-catalyzed cross-couplings using 10 mol% Fe(acac)3 with various functionalized alkenyl iodides and bromides in 1 h at 25 ?C. The aryl-alkenyl cross-coupling reaction mechanism was thoroughly investigated through paramagnetic 1H-NMR, which identified the key role of tris-coordinated ate-iron(II) species in the catalytic process.

Build-up of double carbohelicenes using nitroarenes: Dual role of the nitro functionality as an activating and leaving group

The construction of double carbohelicenes is highly fascinating yet challenging work. Disclosed herein is a streamlined and simplified synthetic route to double carbohelicenes starting from nitroarenes through sequential nitro-activated ortho-C-H arylation, denitrative alkenylation and intramolecular cyclodehydrogenation. In this synthetic strategy, the nitro group plays a dual role namely as a leaving group for the denitrative alkenylation and as an activating group for ortho-C-H arylation, which is distinct from those of aryl halides in a conventional coupling reaction. In this work, the palladium-catalyzed Heck-type alkenylation of nitroarenes has been presented, in which the conventionally inert Ar-NO2 bond is cleaved. This work provides a novel synthetic strategy for polycyclic aromatic hydrocarbons (PAHs). This journal is