932725-54-7

Basic information

• Product Name: methyl 2-(2-((4-methylphenyl)sulfonamido)phenyl)acetate
• Synonyms: methyl 2-(2-((4-methylphenyl)sulfonamido)phenyl)acetate
• CAS NO: 932725-54-7
• Molecular Weight: 319.381
• Mol File: 932725-54-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-(2-((4-methylphenyl)sulfonamido)phenyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(2-((4-methylphenyl)sulfonamido)phenyl)acetate(932725-54-7)
• EPA Substance Registry System: methyl 2-(2-((4-methylphenyl)sulfonamido)phenyl)acetate(932725-54-7)

Safety Data

• Hazardous Substances Data: 932725-54-7(Hazardous Substances Data)

Upstream product

• 3740-52-1 2-(2-nitrophenyl)acetic acid 
• 35613-44-6 2-aminophenylacetic acid methyl ester 
• 98-59-9 p-toluenesulfonyl chloride 
• 30095-98-8 methyl (2-nitrophenyl)acetate 

Relevant articles and documents

Metal-Free Tandem Rearrangement/Lactonization: Access to 3,3-Disubstituted Benzofuran-2-(3H)-ones

A novel metal-free synthesis of 3,3-disubstituted benzofuran-2-(3H)-ones through reacting α-aryl-α-diazoacetates with triarylboranes is presented. Initially, triarylboranes were successfully investigated in α-arylations of α-diazoacetates, however in the presence of a heteroatom in the ortho position, the boron enolate intermediate undergoes an intramolecular rearrangement to form a quaternary center. The intermediate cyclizes to afford valuable 3,3-disubstituted benzofuranones in good yields.