936832-68-7

Basic information

• Product Name: C₁₉H₂₂O₃
• Synonyms: C₁₉H₂₂O₃
• CAS NO: 936832-68-7
• Molecular Weight: 298.382
• Mol File: 936832-68-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₉H₂₂O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₂₂O₃(936832-68-7)
• EPA Substance Registry System: C₁₉H₂₂O₃(936832-68-7)

Safety Data

• Hazardous Substances Data: 936832-68-7(Hazardous Substances Data)

Upstream product

• 103-41-3 (E)-cinnamic acid benzyl ester 

Downstream Products

• 204851-63-8 (R)-2-Benzyl-3-hydroxy-3-methyl-butyric acid 
• 163756-82-9 (R)-2-Benzyl-3-methyl-butyric acid 

Relevant articles and documents

Intermolecular asymmetric reductive aldol reaction of ketones as acceptors promoted by chiral Rh(Phebox) catalyst

The conjugate reduction of cinnamates with hydrosilane and chiral Rh(Phebox-ip) catalyst in the presence of excess acetone is shown to provide the corresponding intermolecular reductive aldol product in extremely high enantioselectivity (up to 98%). Several cinnamates and crotonate substrates and several ketone acceptors were also examined.