94397-83-8Relevant articles and documents
Stereoselective Palladium-Catalyzed Synthesis of (Z)-Trimethyl(2-arylethenyl)silanes by Arylation of (E)-1,2-Bis(trimethylsilyl)ethylene. Effects of Added Halides Compared to Silver Salts
Karabelas, Kostas,Hallberg, Anders
, p. 1773 - 1776 (2007/10/02)
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REACTION OF DIAZONIUM SALTS WITH TRANSITION METALS IX. REACTION OF VINYLTRIMETHYLSILANE WITH ARENEDIAZONIUM TETRAFLUOROBORATES UNDER PALLADIUM(0) CATALYSIS
Kikukawa, Kiyoshi,Ikenaga, Kazutoshi,Kono, Kiyoshi,Toritani, Koji,Wada, Fumio,Matsuda, Tsutomu
, p. 277 - 282 (2007/10/02)
Arenediazonium tetrafluoroborates (ArN2BF4 where Ar = Ph, 4-MeC6H4, 4-BrC6H4, 4-IC6H4 and 4-NO2C6H4) reacted easily with CH2=CHSiMe3 at 25 deg C to give ArCH=CH2, (E)-ArCH=CHSiMe3 and Ar(Me3Si)C=CH2 in excellent yields under palladium(0) catalysis. (E)-ArCH=CHSiMe3 compounds were obtained predominantly and isolated in good yields by using an excess of CH2=CHSiMe3 over ArN2BF4.Protodesilylation of the reaction mixture afforded styrene derivatives.