13515-95-2

Basic information

• Product Name: methyl 2,6-diaminohexanoate hydrochloride
• Synonyms: methyl 2,6-diaminohexanoate hydrochloride;(S)-Methyl 2,6-diaminohexanoate hydrochloride
• CAS NO: 13515-95-2
• Molecular Formula: C₇H₁₇N₂O₂*Cl
• Molecular Weight: 196.67508
• Mol File: 13515-95-2.mol
• Article Data: 31

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: methyl 2,6-diaminohexanoate hydrochloride(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,6-diaminohexanoate hydrochloride(13515-95-2)
• EPA Substance Registry System: methyl 2,6-diaminohexanoate hydrochloride(13515-95-2)

Safety Data

• Hazardous Substances Data: 13515-95-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 657-27-2 L-Lysine hydrochloride 
• 26124-78-7 (S)-α-lysine hydrochloride 
• 17929-90-7 3-aminoazepan-2-one 
• 70-53-1 2,6-diaminohexanoic acid hydrochloride 
• 77-76-9 2,2-dimethoxy-propane 
• 13734-28-6 Boc-Lys-OH 
• 56-87-1 L-lysine 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 98048-25-0 Trt-Lys(Trt)-OMe 
• 69955-44-8 N₂,N₆-dibenzylidene-D,L-lysine methyl ester 
• 943590-99-6 C₂₃H₂₉N₃O₅ 
• 1378349-95-1 methyl 2,6-bis(bis(3-phenylprop-2-yn-1-yl)amino)hexanoate 
• 77611-37-1 (S)-2-((tert-butoxycarbonyl)amino)-6-hydroxyhexanoic acid 
• 374899-60-2 Fmoc-hydroxynorleucine 
• 6033-32-5 (S)-2-amino-6-hydroxyhexanoic acid 
• 55757-60-3 N-α-(tert-butoxycarbonyl)-L-lysine methyl ester 
• 1025905-30-9 C₁₃H₂₀ClN₂O₄P 
• 897932-09-1 (S)-2,6-Bis-(3,4,5-tris-methoxycarbonyloxy-benzoylamino)-hexanoic acid methyl ester 
• 897932-08-0 (S)-2,6-Bis-(3,4-bis-methoxycarbonyloxy-benzoylamino)-hexanoic acid methyl ester 

Relevant articles and documents

Understanding the binding properties of phosphorylated glycoluril-derived molecular tweezers and selective nanomolar binding of natural polyamines in aqueous solution

A modular synthetic platform for the construction of flexible glycoluril-derived molecular tweezers was developed. The binding properties of four exemplary supramolecular hosts obtained via this approach towards 16 organic amines were investigated by means of 1H NMR titration. In this work, we compare the Ka values obtained this way with those of three structurally related molecular tweezers and provide a computational approach towards an explanation of the observed behavior of those novel hosts. The results showcase that certain structural modifications lead to very potent and selective binders of natural polyamines, with observed binding of spermine below 10 nM. This journal is

Novel chiral derivatizing agents for 1H NMR determination of enantiomeric purities of carboxylic acids

(S)-4-(3-Aminopyrrolidin-1-yl)coumarin (1), (S)-4-(3-aminopiperidin-1-yl)coumarin (4), and (S)-4-(3-aminoazepan-1-yl)coumarin (7), prepared from 4-chlorocoumarin and (S)-pyrrolidin-3-amine, (S)-piperidin-3-amine, and (S)-azepan-3-amine, respectively, were proven to be versatile and reliable 1H NMR optical purity determination agents for chiral carboxylic acids.

Supramolecular self-assembly of chiral polyimides driven by repeat units and end groups

Pyromellitic diimides (PMDIs) are effective building blocks for the construction of supramolecular systems but are infrequently used in comparison with other electron-deficient aromatic systems. We report PMDI-based chiral polyimides that form polymeric supramolecular systems with unique self-assembly features that show time-dependent spectroscopic behaviour. Extensive investigations revealed the driving forces for the self-assembly of the polyimides. One is the complementary aromatic π-π stacking between electron-accepting PMDI and electron-donating phenyl ring in the polymer backbones, and another is the hydrogen bonding interactions of the end groups. The self-assembly is readily disrupted by guest molecules with strong associations with the PMDI and the end groups. The introduction of flexible arylether diimides into the PMDI-based copolymer backbones and the sequence of PMDIs and arylether diimides in the copolymer backbones significantly influence the self-assembly of the polyimides. The results elucidate the mechanisms of polymeric self-assembly of chiral polyimides, providing important information for the development of materials based on polymeric supramolecular systems with properties and functions regulated by composition, sequence and end groups.