85551-57-1Relevant articles and documents
Conformationally rigid chiral pyridine N-oxides as organocatalyst: Asymmetric allylation of aldehydes
Gnanamani, Elumalai,Someshwar, Nagamalla,Ramanathan, Chinnasamy Ramaraj
, p. 2101 - 2106 (2012)
A pyridine unit with a conformationally rigid chiral backbone has been designed and synthesized in an enantiomerically pure form to utilize in the Lewis base-catalyzed Sakurai-Hosomi-Denmark-type allylation reaction. The chiral pyridine N-oxide in 1:1 mix
Catalytic asymmetric synthesis of homoallylic alcohols: Chiral amplification and chiral poisoning in a titanium/BINOL catalyst system
Faller,Sams,Liu
, p. 1217 - 1218 (1996)
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Chiral bipyridine-annulated bicyclo[3.3.1]nonane N-oxide organocatalysts for stereoselective allylation and hydrosilylation reactions
?eimyt?, Simona,Ston?ius, Sigitas
supporting information, (2020/12/21)
The synthesis of chiral C2-symmetric bis(bipyridine N,N′-dioxide) and bis(bipyridine N-monooxide) derivatives featuring bipyridine-annulated bicyclo[3.3.1]nonane framework is reported. The new Lewis basic bipyridine N,N′-dioxides exhibited good
Highly Enantioselective Allylation Reactions of Aldehydes with Allyltrimethylsilane Catalyzed by a Chiral Oxazaborolidinium Ion
Kim, Taehyeong,Jeong, Hye-Min,Venkateswarlu, Anipireddy,Ryu, Do Hyun
supporting information, p. 5198 - 5201 (2020/07/15)
A highly enantioselective allylation reaction of aldehydes with silyl reagents was developed for the synthesis of a variety of chiral homoallylic alcohols. In the presence of a chiral oxazaborolidinium ion (COBI) catalyst, the reaction proceeded in high yield (up to 99percent) with excellent asymmetric induction (up to 99percent ee).
