68820-12-2

Basic information

• Product Name: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-
• Synonyms: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-;7-tosyl-7-azabicyclo[4.1.0]heptane
• CAS NO: 68820-12-2
• Molecular Formula: C₁₃H₁₇NO₂S
• Molecular Weight: 251.34458
• Mol File: 68820-12-2.mol
• Article Data: 88

Chemical Properties

• Melting Point: 55-56 °C
• Boiling Point: 386.0±35.0 °C(Predicted)
• Appearance: /
• Density: 1.257±0.06 g/cm3(Predicted)
• PKA: -6.46±0.20(Predicted)
• CAS DataBase Reference: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-(68820-12-2)
• EPA Substance Registry System: 7-Azabicyclo[4.1.0]heptane, 7-[(4-Methylphenyl)sulfonyl]-(68820-12-2)

Safety Data

• Hazardous Substances Data: 68820-12-2(Hazardous Substances Data)

Upstream product

• 127-65-1 chloroamine-T 
• 110-83-8 cyclohexene 
• 41085-71-6 bromamine T 
• 71996-32-2 N-(5λ⁴-dibenzo[b,d]thiophen-5-ylidene)-4-methylbenzenesulfonamide 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 7080-50-4 chloramine T trihydrate 
• 1058-14-6 N-p-tolylsulfonylphosphine imide 
• 1338062-05-7 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide 
• 21849-40-1 dibromamine-T 
• 144-86-5 N-chloro-4-methylbenzenesulfonamide 
• 98-59-9 p-toluenesulfonyl chloride 
• 286-18-0 7-azabicyclo[4.1.0]heptane 
• 70-55-3 toluene-4-sulfonamide 
• 286-20-4 cyclohexane-1,2-epoxide 

Downstream Products

• 132161-94-5 (+/-)-trans-N-(2-cyano-cyclohexyl)-4-methyl-benzene sulfonamide 
• 68820-01-9 2-(phenylselanyl)-N-tosylcyclohexanamine 
• 76475-12-2 N-(2-chlorocyclohexyl)-4-methylbenzenesulfonamide 
• 871086-18-9 4-Methyl-N-[(1R,2R)-2-((R)-1-phenyl-ethylamino)-cyclohexyl]-benzenesulfonamide 
• 871086-12-3 4-Methyl-N-[(1S,2S)-2-((R)-1-phenyl-ethylamino)-cyclohexyl]-benzenesulfonamide 
• 58107-57-6 4-methyl-N-(2-oxo-cyclohexyl)-benzenesulfonamide 

Relevant articles and documents

Manganese-catalyzed aziridination of olefins with chloramine-T in water and buffered aqueous solutions

A water-soluble, manganese-porphyrin complex was used to catalytically generate aziridines from olefins in moderate to good yields (up to 93%) upon optimization at room temperature and in aqueous media. Reactions using chloramine-T at slightly acidic to n

Make It Green: Copper-Catalyzed Olefin Aziridination in Water with an Iminoiodonane

The copper complex Tp(CF3)2,BrCu(NCMe) efficiently catalyses the aziridination of olefins in water using PhI=NTs as the nitrene source, with identical activity than that observed when using dichloromethane as the solvent, under the same experim

Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents

Recent research has highlighted the key role played by the electron affinity of the active metal-nitrene/imido oxidant as the driving force in nitrene additions to olefins to afford valuable aziridines. The present work showcases a library of Co(II) reage