71026-66-9

Basic information

• Product Name: 4-(TERT-BUTOXYCARBONYLAMINO)ANILINE
• Synonyms: tert-butyl N-(4-aMinophenyl)carbaMate;N-Boc-benzene-1,4-diaMine;Carbamicacid,N-(4-aminophenyl)-,1,1-dimethylethylester;N-Boc-p-phenylenediamine >=97.0% (NT);BOC-1,4-PHENYLENEDIAMINE;(4-AMINO-PHENYL)-CARBAMIC ACID TERT-BUTYL ESTER;4-(TERT-BUTOXYCARBONYLAMINO)ANILINE;N-BOC-P-PHENYLENEDIAMINE
• CAS NO: 71026-66-9
• Molecular Formula: C₁₁H₁₆N₂O₂
• Molecular Weight: 208.26
• EINECS: 275-132-7
• Product Categories: N-BOC
• Mol File: 71026-66-9.mol
• Article Data: 74

Chemical Properties

• Melting Point: 113-115 °C
• Boiling Point: 295.4 °C at 760 mmHg
• Flash Point: 132.5 °C
• Appearance: beige to brownish crystalline powder
• Density: 1.152 g/cm³
• Vapor Pressure: 0.002mmHg at 25°C
• Refractive Index: 1.583
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: soluble in Methanol
• PKA: 13.49±0.70(Predicted)
• BRN: 2969618
• CAS DataBase Reference: 4-(TERT-BUTOXYCARBONYLAMINO)ANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(TERT-BUTOXYCARBONYLAMINO)ANILINE(71026-66-9)
• EPA Substance Registry System: 4-(TERT-BUTOXYCARBONYLAMINO)ANILINE(71026-66-9)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-43-50/53
• Safety Statements: 36/37-60-61
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 71026-66-9(Hazardous Substances Data)

Usage

Uses

N-Boc-p-phenylenediamine can be used as:A reactant to prepare perylene monoimide-based dyes for dye-sensitized solar cell applications.A starting material to synthesize covalent organic frameworks, which are used as proton exchange membranes for hydrogen fuel cell applications.A reactant in the synthesis of bestatin derived hydroxamic acids as potent pan-HDAC inhibitors.

InChI:InChI=1/C11H16N2O2/c1-11(2,3)15-10(14)13-9-6-4-8(12)5-7-9/h4-7H,12H2,1-3H3,(H,13,14)

Upstream product

• 34619-03-9 tert-butyldicarbonate 
• 106-50-3 1,4-phenylenediamine 
• 86031-24-5 O-(tert-butoxycarbonyl)hydroxylamine 
• 2733-41-7 4-nitrobenzoyl azide 
• 24608-52-4 tert-butyl chloroformate 
• 179321-49-4 N-(tert-butoxycarbonyl)-4-aminocyclohexanone 
• 54840-15-2 4-N-tert-butoxycarbonylaminophenol 
• 851651-82-6 tert-butyl (4-(vinylsulfonamido)phenyl)carbamate 
• 395639-03-9 bis(1,1-dimethylethyl)(4-nitrophenyl)imidocarbonate 
• 100-01-6 4-nitro-aniline 
• 24424-99-5 di-tert-butyl dicarbonate 
• 18437-63-3 tert-butyl N-(4-nitrophenyl)carbamate 

Downstream Products

• 160291-53-2 tert-butyl N-<4-(7-diethylamino-2-oxo-2H-chromene-3-carboxamido)phenyl>carbamate 
• 183740-30-9 3-[4-(N-BOC-amino)-phenylamino]-2-cyano-3-methylmercapto-acrylonitrile 
• 390406-02-7 (4-{3-[2-(3,4-dichloro-phenyl)-2-hydroxy-ethyl]-3-isopropyl-ureido}-phenyl)-carbamic acid tert-butyl ester 
• 914489-91-1 tert-butyl (4-benzamidophenyl)carbamate 
• 912838-01-8 butyl 5-(3-buten-1-yl)-1-{4-[(tert-butoxycarbonyl)amino]phenyl}-1H-1,2,3-triazole-4-carboxylate 
• 936576-80-6 1-(tert-butyloxycarbamido)-4-[2,3-di(isopropylmercapto)benzamido]benzene 
• 1351521-10-2 N₁-(tert-butoxycarbonyl)-N-4-(4-nitrophenylsulfonyl)-phenylene-1,4-diamine 
• 851651-82-6 tert-butyl (4-(vinylsulfonamido)phenyl)carbamate 
• 675136-71-7 N,N-dipropyl-N'-boc-1,4-phenylenediamine 
• 861851-04-9 [4-(6-chloropyrimidin-4-ylamino)-phenyl]carbamic acid tert-butyl ester 
• 861851-02-7 {4-[6-(2-methyl-2,3-dihydro-benzofuran-5-yl)-pyrimidin-4-yl-amino]-phenyl}-carbamic acid tert-butyl ester 
• 482305-94-2 tert-Butyl 4-[(3-{[(5-chloro-thien-2-yl)carbonyl]amino}-2-hydroxypropyl)amino]-phenyl-carbamate 
• 915086-27-0 {4-[(1-cyano-1-methylethyl)amino]phenyl}carbamic acid tert-butyl ester 
• 380885-14-3 benzamide, 3-[[[[[(4-aminophenyl)amino]carbonyl]-amino]sulfonyl]amino]-N-(3,4-difluorophenyl)-4-methoxy-, mono(trifluoroacetate) 

Relevant articles and documents

Combined Intrinsic and Extrinsic Proton Conduction in Robust Covalent Organic Frameworks for Hydrogen Fuel Cell Applications

Developing new materials for the fabrication of proton exchange membranes (PEMs) for fuel cells is of great significance. Herein, a series of highly crystalline, porous, and stable new covalent organic frameworks (COFs) have been developed by a stepwise synthesis strategy. The synthesized COFs exhibit high hydrophilicity and excellent stability in strong acid or base (e.g., 12 m NaOH or HCl) and boiling water. These features make them ideal platforms for proton conduction applications. Upon loading with H3PO4, the COFs (H3PO4?COFs) realize an ultrahigh proton conductivity of 1.13×10?1 S cm?1, the highest among all COF materials, and maintain high proton conductivity across a wide relative humidity (40–100 %) and temperature range (20–80 °C). Furthermore, membrane electrode assemblies were fabricated using H3PO4?COFs as the solid electrolyte membrane for proton exchange resulting in a maximum power density of 81 mW cm?2 and a maximum current density of 456 mA cm?2, which exceeds all previously reported COF materials.

Thiazole ring-containing amide compounds as well as preparation method and application thereof

The invention discloses thiazole ring-containing amide compounds as well as a preparation method and application thereof, and belongs to the field of chemical technologies and pesticides. According to the present invention, p-phenylenediamine is adopted as a raw material to synthesize a series of the thiazole ring-containing amide compounds, and the synthesized thiazole ring-containing amide compounds have good inhibition effects on Xanthomonas oryzae pv.Oryza (Xoo), Xanthomonas oryzae pv.Oryzcola (Xoc) and Xanthomonas axonophora pv.Citri (Xac) in agricultural diseases and insect pests, and can be used for preparing the anti-plant bacterium agent.

Direct and Divergent Solid-Phase Synthesis of Azobenzene and Spiropyran Derivatives

Here, we report a solid-phase approach to synthesize azobenzene and spiropyran derivatives. The divergent synthesis process requires no purification steps to obtain the desired product with a 28-55% yield, depending on the specific compound. For the spiropyran compounds, solid-phase resin cleavage is performed under mild conditions to minimize spiropyran ring opening. The solid-phase method enables the synthesis of a library of azobenzene and spiropyran derivatives without the need to develop purification strategies for each derivative.